Late Transition Metal Polymerization Catalysis.pdf

Late Transition Metal Polymerization Catalysis PDF

Bernhard Rieger

Date de parution

Self-assembled heterogeneous late … Recently, we developed heterogeneous late transition–metal catalysts which were prepared by the direct reaction of Fe 3 +, Co 2 +, or Ni 2 + ion-exchanged fluorotetrasilicic mica and an appropriate ligand , , , . The active component is readily formed by the activation of the procatalyst by a conventional alkyl aluminum compound and showed a high catalytic activity. Moreover, the catalysts

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Late Transition Metal Polymerization Catalysis.pdf

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Reaction of Vinyl Chloride with Late Transition … The reactions of vinyl chloride (VC) with representative late metal, single-site olefin dimerization and polymerization catalysts have been investigated. VC coordinates more weakly than ethylene or propylene to the simple catalyst (Me2bipy)PdMe+ (Me2bipy = 4,4‘-Me2-2,2‘-bipyridine). Insertion rates of (Me2bipy)Pd(Me)(olefin)+ species vary in the order VC > ethylene > propylene.